NSFileManager unique file names

Create your own file name:

CFUUIDRef uuid = CFUUIDCreate(NULL);
CFStringRef uuidString = CFUUIDCreateString(NULL, uuid);
CFRelease(uuid);
NSString *uniqueFileName = [NSString stringWithFormat:@"%@%@", prefixString, (NSString *)uuidString];
CFRelease(uuidString);

A simpler alternative proposed by @darrinm in the comments:

NSString *prefixString = @"MyFilename";

NSString *guid = [[NSProcessInfo processInfo] globallyUniqueString] ;
NSString *uniqueFileName = [NSString stringWithFormat:@"%@_%@", prefixString, guid];

NSLog(@"uniqueFileName: '%@'", uniqueFileName);

NSLog output:
uniqueFileName: ‘MyFilename_680E77F2-20B8-444E-875B-11453B06606E-688-00000145B460AF51’

Note: iOS6 introduced the NSUUID class which can be used in place of CFUUID.

NSString *guid = [[NSUUID new] UUIDString];