What you have is the most clear option.
But you could shorten it using array_fill_keys, like this:
$database = array_fill_keys(
array('dbdriver', 'dbhost', 'dbname', 'dbuser', 'dbpass'), '');
But if the user has to fill the values anyway, you can just leave the array empty, and just provide the example code in index.php. The keys will automatically be added when you assign a value.