This should do what you need it to. It will fill the entire bitmap with the specified color.
Bitmap Bmp = new Bitmap(width, height);
using (Graphics gfx = Graphics.FromImage(Bmp))
using (SolidBrush brush = new SolidBrush(Color.FromArgb(redvalue, greenvalue, bluevalue)))
{
gfx.FillRectangle(brush, 0, 0, width, height);
}