With OS > 3.0 you can do this:
//you need this import
#import <QuartzCore/QuartzCore.h>
[imageView.layer setBorderColor: [[UIColor blackColor] CGColor]];
[imageView.layer setBorderWidth: 2.0];
With OS > 3.0 you can do this:
//you need this import
#import <QuartzCore/QuartzCore.h>
[imageView.layer setBorderColor: [[UIColor blackColor] CGColor]];
[imageView.layer setBorderWidth: 2.0];