The code sample you provided should work.
Try this:
UIColor uicolor = [[UIColor greenColor] retain];
CGColorRef color = [uicolor CGColor];
int numComponents = CGColorGetNumberOfComponents(color);
if (numComponents == 4)
{
const CGFloat *components = CGColorGetComponents(color);
CGFloat red = components[0];
CGFloat green = components[1];
CGFloat blue = components[2];
CGFloat alpha = components[3];
}
[uicolor release];