@ResponseStatus(HttpStatus.OK) means that the request will return OK if the handling method returns normally (this annotation is redundant for this case, as the default response status is HttpStatus.OK). If the method throws an exception, the annotation does not apply; instead, the status will be determined by Spring using an exception handler.
How can I handle multiple response statuses depending on conditions in the same method?
That question has already been asked.
Can I change the Response Status on occurrence of any exception
You have two choices. If the exception class is one of your own, you could annotate the exception class with @ResponseStatus. The other choice is to provide the controller class with an exception handler, annotated with @ExceptionHandler, and have the exception handler set the response status.