Looking in the jQuery doc and code, I don’t see any way to cancel a jQuery deferred.
Instead, you probably need a way in your resolveWith handler to know that a subsequent ajax call has already been fired and this ajax call should ignore its result. You could do that with a globally incrementing counter. At the start of your ajax call, you increment the counter and then you grab the value into a local variable or put it as a property on the ajax object. In your resolveWith handler, you check to see if the counter still has the same value as when your ajax call started. If not, you ignore the result. If it does, no new ajax calls have been fired so you can process the result.
Alternately, you could refuse to fire a new ajax call while one is in flight already so you never had more than one in flight at a time. When the one finishes, you could either just use that result or fire the next one if desired.