You could set the BorderThickness
for DataGridCell
to 0
<DataGrid ...
SelectionUnit="FullRow">
<DataGrid.CellStyle>
<Style TargetType="DataGridCell">
<Setter Property="BorderThickness" Value="0"/>
<!-- Update from comments.
Remove the focus indication for the selected cell -->
<Setter Property="FocusVisualStyle" Value="{x:Null}"/>
</Style>
</DataGrid.CellStyle>
<!-- ... -->
</DataGrid>