Your dataframe has four columns like so df[,c(1,2,3,4)].
Note the first comma means keep all the rows, and the 1,2,3,4 refers to the columns.
To change the order as in the above question do df2[,c(1,3,2,4)]
If you want to output this file as a csv, do write.csv(df2, file="somedf.csv")