You will have to use a class, but don’t worry, it’s pretty simple. First we’ll assign your :hover rules to not only apply to physically-hovered links, but also to links that have the classname hovered.
a:hover, a.hovered { color: #ccff00; }
Next, when you click #btn, we’ll toggle the .hovered class on the #link.
$("#btn").click(function() {
$("#link").toggleClass("hovered");
});
If the link has the class already, it will be removed. If it doesn’t have the class, it will be added.