Just set WindowStartupLocation, Height, Width, Left, and Top in xaml:
<Window x:Class="WpfApplication1.Window1"
xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
Title="Window1"
Height="500" Width="500"
WindowStartupLocation="Manual"
Left="0" Top="0">
</Window>