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Yes it’s possible using a claim based authentication. It’s integrated to .Net 4.5 now (before it was called WIF).
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You can use Thinktucture, which is a very robust authentication provider it has a full example on how to integrate ADFS. Here is a link for it.
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Here is another way to do it for an MVC4 app – MVC 4 and ADFS integration guide included
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Here’s a solution for MVC5 Web app using ADFS On-Premises Organizational Auth and Visual Studio 2013 localhost development
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If you don’t want to use ADFS you can use the
ActiveDirectoryMembershipProvider. It works with Windows authentication and here’s an post of using it with Forms authentication – Chris Schiffhauer – Implement Active Directory Authentication in ASP.NET MVC 5: